Alyssa Jane Venable, 23, was lodged in the Rappahannock Regional Jail on Tuesday, June 11.
Venable is accused of killing three of her roommates, whose bodies were found in a home on the 10500 block of White Street Court on June 4, the county sheriff said.
Venable was captured with help from the US Marshals Service on Thursday, June 6 around 5:45 p.m., following a pursuit that reached speeds of up to 100 mph on I-86 in Steuben County, NY, the Spotsylvania County Sheriff's Office said.
Troopers deployed a tire deflation device, causing Venable to crash, authorities said. She was arrested and taken to the hospital as a precaution. No citizens or law enforcement were injured.
Venable has been charged with three counts of second-degree murder and use of a firearm in the commission of a felony.
The sheriff's office identified the victims as Robert John McGuire 77, Gregory Scott Powell, 60, and, Carol Anne Reese, 65. They were found by deputies performing a welfare check having suffered upper-body trauma, authorities said previously.
Click here to follow Daily Voice Falls Church and receive free news updates.